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protein on PVDF ultrafiltration membrane fouling behavior under different pH conditions: interface adhesionforce and XDLVO theory analysis

Xudong WANG,Miao ZHOU,Xiaorong MENG,Lei WANG,Danxi HUANG

《环境科学与工程前沿(英文)》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0855-9

摘要: pH values of the BSA solution significantly impact the process of membrane fouling. Dramatic flux decline is caused by membrane–BSA adhesion force at start of filtration. XDLVO theory shows the polar or Lewis acid–base interaction plays a major role in membrane fouling. To further determine the fouling behavior of bovine serum albumin (BSA) on different hydrophilic PVDF ultrafiltration (UF) membranes over a range of pH values, self-made atomic force microscopy (AFM) colloidal probes were used to detect the adhesion forces of membrane–BSA and BSA–BSA, respectively. Results showed that the membrane–BSA adhesion interaction was stronger than the BSA–BSA adhesion interaction, and the adhesion force between BSA–BSA-fouled PVDF/PVA membranes was similar to that between BSA–BSA-fouled PVDF/PVP membranes, which indicated that the fouling was mainly caused by the adhesion interaction between membrane and BSA. At the same pH condition, the PVDF/PVA membrane–BSA adhesion force was smaller than that of PVDF/PVP membrane–BSA, which illustrated that the more hydrophilic the membrane was, the better antifouling ability it had. The extended Derjaguin–Landau–Verwey–Overbeek (XDLVO) theory predicts that the polar or Lewis acid–base (AB) interaction played a dominant role in the interfacial free energy of membrane–BSA and BSA–BSA that can be affected by pH. For the same membrane, the pH values of a BSA solution can have a significant impact on the process of membrane fouling by changing the AB component of free energy.

关键词: PVDF membrane     Membrane fouling     Adhesion force     Protein     Interfacial free energy    

On the applicability of different adhesion models in adhesive particulate flows

Guanqing LIU, Shuiqing LI, Qiang YAO,

《能源前沿(英文)》 2010年 第4卷 第2期   页码 280-286 doi: 10.1007/s11708-009-0062-5

摘要: An adhesion map provides quantitative criteria for the appropriate selection of adhesion models applicable to a specific adhesive contact problem of fine particles in complex particulate flows. In this paper, three different general adhesion models are used to construct adhesion maps. The applicable regimes on the adhesion map for different approximate adhesion models are determined according to their underlying limitations. It is found that the choice of general model has limited influence on the structure of a constructed adhesion map. On the contrary, the regime of application for each approximate model is sensitive to the approximation level. A three-dimensional, more intuitive adhesion map based on physical parameters of particles is also built. Finally, recent applications of adhesion models in discrete element method (DEM) investigations of fine-particle flow dynamics are briefly discussed.

关键词: adhesive contact     van der Waals force     adhesion model     adhesion map     DEM    

大力测量技术的新进展——附着式超轻型大力传感器

沈久珩

《中国工程科学》 2001年 第3卷 第10期   页码 22-27

摘要:

大力传感器是现代重型装备的高科技电子信息器件。文章围绕重型大力传感器的微型化问题论述了重型装备大力测量的意义、特征及发展,讨论了大力分流测量的物理模型,介绍了作者发明的超轻型附着式大力传感器及其工程应用。

关键词: 重型装备     大力传感器     支承式     附着式     电阻应变计     分流测量    

Materials and surface engineering to control bacterial adhesion and biofilm formation: A review of recent

Huan GU, Dacheng REN

《化学科学与工程前沿(英文)》 2014年 第8卷 第1期   页码 20-33 doi: 10.1007/s11705-014-1412-3

摘要: Bacterial adhesion to surfaces and subsequent biofilm formation are a leading cause of chronic infections and biofouling. These processes are highly sensitive to environmental factors and present a challenge to research using traditional approaches with uncontrolled surfaces. Recent advances in materials research and surface engineering have brought exciting opportunities to pattern bacterial cell clusters and to obtain synthetic biofilms with well-controlled cell density and morphology of cell clusters. In this article, we will review the recent achievements in this field and comment on the future directions.

关键词: surface engineering     materials     bacterial adhesion     biofilm     control     review    

Effect of electrokinetic property of charged polyether sulfone membrane on bovine serum albumin fouling behavior

Xiaorong Meng, Shanshan Huo, Lei Wang, Xudong Wang, Yongtao Lv, Weiting Tang, Rui Miao, Danxi Huang

《环境科学与工程前沿(英文)》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0907-9

摘要: Negatively charged CMPES and positively charged QAPES membranes were fabricated. Charge modification reduced the adhesion forces between PES UF membranes and BSA. QAPES-BSA / was weaker than that of CMPES-BSA at pH 3 and on the contrary at pH 9. Flux decline rate was positively correlated with the adhesion forces of membrane-BSA. Variation of adhesion was consistent with that of potential absolute values. Negatively charged carboxymethylated polyethersulfone (CMPES) and positively charged quaternized polyethersulfone (QAPES) ultrafiltration (UF) membranes were prepared by bulk chemical modification and non-solvent induced phase separation method. The effects of PES membrane interfacial electrokinetic property on the bovine serum albumin (BSA) membrane fouling behavior were studied with the aid of the membrane-modified colloidal atomic force microscopy (AFM) probe. Electrokinetic test results indicated that the streaming potential (D ) of QAPES membrane was not consistent with its expected value, however, within the pH range of 3–10, the potentials of two charged-modified PES membranes were more stable than the unmodified membrane. When pH value was 3, 4.7 or 9, the interaction behavior between charged PES membrane and BSA showed that there was significant linear correlation between the jump distance of membrane-BSA adhesion force ( ) and the potential absolute value. Charged modification significantly reduced the adhesion of PES membrane-BSA, and the adhesion data was good linear correlated with the flux decline rate in BSA filtration process, especially reflected in the CMPES membrane. The above experimental facts proved that the charged membrane interfacial electric double layer structure and its electrokinetic property had strong ties with the protein membrane fouling behavior.

关键词: Charged PES UF membrane     BSA     Electrokinetic characterization     Adhesion force     Jump distance    

Effect of interface adhesion factor on the bearing capacity of strip footing placed on cohesive soil

《结构与土木工程前沿(英文)》 2021年 第15卷 第6期   页码 1494-1503 doi: 10.1007/s11709-021-0768-y

摘要: The problem related to bearing capacity of footing either on pure soil or on pure rock mass has been investigated over the years. Currently, no study deals with the bearing capacity of strip footing on a cohesive soil layer overlying rock mass. Therefore, by implementing the lower bound finite element limit analysis in conjunction with the second-order cone programming and the power cone programming, the ultimate bearing capacity of a strip footing located on a cohesive soil overlying rock mass is determined in this study. By considering the different values of interface adhesion factor (αcr) between the cohesive soil and rock mass, the ultimate bearing capacity of strip footing is expressed in terms of influence factor (If) for different values of cohesive soil layer cover ratio (Tcs/B). The failure of cohesive soil is modeled by using Mohr−Coulomb yield criterion, whereas Generalized Hoek−Brown yield criterion is utilized to model the rock mass at failure. The variations ofIf with different magnitudes of αcr are studied by considering the influence of the rock mass strength parameters of beneath rock mass layer. To examine stress distribution at different depths, failure patterns are also plotted.

关键词: bearing capacity     soil-rock interface     Hoek−Brown yield criterion     plasticity     limit analysis    

Study on the cohesion and adhesion of hot-poured crack sealants

Meng GUO, Yiqiu TAN, Xuesong DU, Zhaofeng LV

《结构与土木工程前沿(英文)》 2017年 第11卷 第3期   页码 353-359 doi: 10.1007/s11709-017-0400-3

摘要: Filling crack sealant is a main method to repair cracking of pavement. The cohesion and adhesion of crack sealant directly determine its service performance and durability. However, the competitive mechanism of cohesion and adhesion failure modes is not clear currently. This research proposed two methods to evaluate cohesion and adhesion of crack sealant, and analyzed the influence of temperature on cohesion and adhesion. The effect of moisture on low-temperature performance of crack sealant was also be evaluated by conducting a soaking test. Results show that with the decrease of temperature, the cohesion force of crack sealant increases significantly, while the adhesion force changes little. There is a critical temperature at which the cohesion force equals the adhesion force. When the temperature is higher, the adhesion force will be greater than cohesion force, and the cohesion failure will happen more easily. In contrast, the adhesion failure will happen more easily when the temperature is lower than the critical value. Soaking in 25 °C water for 24–48 hours will slightly improve the low-temperature tension performance of crack sealant. However, soaking in 60 °C water for 24 hours will decrease the failure energy of low-temperature tension and damage the durability of crack sealant.

关键词: crack sealant     concrete pavement     cohesion     adhesion     moisture damage    

CD176 single-chain variable antibody fragment inhibits the adhesion of cancer cells to endothelial cells

null

《医学前沿(英文)》 2016年 第10卷 第2期   页码 204-211 doi: 10.1007/s11684-016-0443-1

摘要:

CD176 (Thomsen-Friedenreich antigen) is a tumor-associated carbohydrate epitope (glycotope) functionally involved in blood spread and liver metastasis of cancer cells by mediating the adhesion of cancer cells to endothelial cells and hepatocytes, respectively. CD176 could be a promising target for antitumor immunotherapy. We applied B lymphocytes obtained from mice immunized with CD176 antigen and constructed a phage display library. A positive clone of CD176 single-chain variable antibody fragment (scFv) was successfully screened from this library. The CD176 scFv was expressed in Escherichia coli and purified. The purified scFv can bind to the natural CD176 expressed on the surface of cancer cells. Furthermore, the CD176 scFv inhibits the adhesion of CD176+ cancer cells to endothelial cells and hepatocytes. This CD176 scFv provides a basis for future development of recombinant CD176-specific antibodies that can be used in therapeutic application.

关键词: CD176     Thomsen-Friedenreich antigen     scFv     cancer     therapy     adhesion     metastasis    

Modeling limit force capacities of high force to volume lead extrusion dampers

《结构与土木工程前沿(英文)》 2021年 第15卷 第3期   页码 609-622 doi: 10.1007/s11709-021-0724-x

摘要: Lead extrusion dampers are supplemental energy-dissipation devices that are used to mitigate seismic structural damage. Small volumetric sizes and high force capacities define high-force-to-volume (HF2V) devices, which can absorb significant response energy without sacrificial damage. However, the design of such devices for specific force capacities has proven difficult based on the complexities of their internal reaction mechanisms, leading to the adoption of empirical approaches. This study developed upper- and lower-bound force capacity estimates from analytical mechanics based on direct and indirect metal extrusion for guiding design. The derived equations are strictly functions of HF2V device geometric parameters, lead material properties, and extrusion mechanics. The upper-bound estimates from direct and indirect extrusion are denoted as (FUB,1, FUB,2) and (FUB,3, FUB,4), respectively, and the lower-bound estimates are denoted as (FLB, FLB,1) based on the combination of extrusion and friction forces. The proposed models were validated by comparing the predicted bounds to experimental force capacity data from 15 experimental HF2V device tests. The experimental device forces all lie above the lower-bound estimates (FLB, FLB,1) and below the upper-bound estimates (FUB,1, FUB,2, FUB,4). Overall, the (FLB, FUB,2) pair provides wider bounds and the (FLB,1, FUB,4/FUB,1) pair provides narrower bounds. The (FLB,1, FUB,1) pair has a mean lower-bound gap of 36%, meaning the lower bound was 74% of the actual device force on average. The mean upper-bound gap was 33%. The bulge area and cylinder diameter of HF2V devices are key parameters affecting device forces. These relatively tight bounds provide useful mechanics-based predictive design guides for ensuring that device forces are within the targeted design range after manufacturing.

关键词: extrusion     lead dampers     upper and lower bound     analytical modelling     limit force    

Plated contacts for solar cells with superior adhesion strength to screen printed solar cells

R. CHEN,S. WANG,A. WENHAM,Z. SHI,T. YOUNG,J. JI,M. EDWARDS,A. SUGIANTO,L. MAI,S. WENHAM,C. CHONG

《能源前沿(英文)》 2017年 第11卷 第1期   页码 72-77 doi: 10.1007/s11708-016-0428-4

摘要: The improvement of adhesion strength and durability of plated contacts is required for cell manufacturers to gain confidence for large-scale manufacturing. To overcome weak adhesion at the metal/Si interface, new approaches were developed. These involve the formation of laser-ablated anchor points, or grooves in the extreme case of overlapping anchor points, in the heavily doped silicon surface. When plated, these features greatly strengthen the mechanical adhesion strength of the metal. A stylus-based adhesion tester was developed specifically for evaluating the effectiveness of plated contacts to smooth silicon surfaces. The use of such a tester was also extended in this work to textured and roughened surfaces to allow evaluation of different metal contacting approaches. The adhesion strengths for various metal contacting schemes were evaluated, including screen-printed silver contacts, nickel/copper (Ni/Cu) light-induced plated (LIP) contacts for laser-doped selective emitter (LDSE) cells, buried-contact solar cells (BCSCs), and Ni/Cu LIP contacts formed with laser-ablated anchoring points in selective emitter (LAASE) cells. The latter has superior adhesion strength. The standard “peel test” of the industry was compared to the stylus-based adhesion testing, with the latter shown value for testing metal contacts on smooth surfaces but with caution needed for use with textured or roughened surfaces.

关键词: light-induced plating     metal adhesion strength     copper plating     metal contacts     solar cell durability     silicon solar cells    

Development and road performance of clear asphalt with high transparency and adhesion

《结构与土木工程前沿(英文)》 2023年 第17卷 第2期   页码 238-255 doi: 10.1007/s11709-022-0898-x

摘要: Clear asphalt (CA) currently used in light-colored asphalt mixtures (LCAM) exhibits poor transparency and adhesion. Therefore, a highly transparent CA (HCA) modified using a silane coupling agent (KH550) was prepared. Furthermore, LCAM was prepared by mixing CA and limestone aggregates. The properties of the HCA and ordinary CA (OCA) were characterized using conventional asphalt tests, optical tests, pull-off tests, ultraviolet aging tests, dynamic shear rheometry, Fourier-transform infrared spectroscopy, differential scanning calorimetry, and scanning electron microscopy. Whereas Marshall, moisture resistance, wheel tracking, trabecular bending, and British pendulum tests were employed for the LCAM. The transmittance and spectral reflectance of the HCA were 123.30 and 3.74 times greater than those of the OCA, respectively. The complex modulus and viscosity-aging index of the HCA were 48% and 53% less than those of the OCA, respectively. After modification with KH550, the Marshall stability ratio, tensile strength ratio, and flexural strain of the HCA-prepared LCAM increased by 12.92%, 25.06%, and 23.90%, respectively. However, the rutting resistance of the HCA-prepared LCAM was 14.3% less than that of the OCA-prepared LCAM. The comprehensive performances of the HCA and HCA-prepared LCAM were 49.2% and 10.3% greater than those of the OCA and OCA-prepared LCAM, respectively, indicating a high application value in the future.

关键词: light-colored asphalt pavement     orthogonal test     road performance     spectral reflectance     silane-coupling agent    

Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

《机械工程前沿(英文)》 2010年 第5卷 第4期   页码 412-417 doi: 10.1007/s11465-010-0114-x

摘要: The behaviors of electrode displacement and force during spot welding under various conditions, such as different weld currents, electrode forces, and welding times, were studied. Tests were conducted on a 170?kVA MFDC spot welder. Data were collected via a multichannel high-speed data acquisition system and were analyzed with MATLAB. Behaviors of 5182 aluminum and mild steel in spot welding were compared. Results show that nugget expansion rate does not reach zero for aluminium as it does for mild steel as nugget grew to a certain size. A linear relationship is found between the nugget size and maximum expansion that facilitates online weld quality evaluation. An electrode force peak is observed and believed relevant to the sufficient nugget size.

关键词: aluminum     electrode displacement     electrode force     nugget size     data acquisition    

Visualization of force networks in 2D dense granular materials

Jianguo LIU, Qicheng SUN, Feng JIN,

《结构与土木工程前沿(英文)》 2010年 第4卷 第1期   页码 109-115 doi: 10.1007/s11709-010-0003-8

摘要: Dense granular matter is a conglomeration of discrete solid and closely packed particles. As subjected to external loadings, the stress is largely transmitted by heavily stressed chains of particles forming a sparse network of larger contact forces. To understand the structure and evolution of force chains, a photoelastic technique was improved for determining stresses and strains in the assemblies of photoelastic granular disks in this paper. A two-dimensional vertical slab was designed. It contains 7200 polydispersed photoelastic disks and is subjected to a localized probe penetrating at the top of the slab to mimic the cone penetration test. The interparticle contact force distribution was found a peak around the mean value, a roughly exponential tail for greater force and a dip toward zero for smaller force. The force chain network around the probe tip was depicted, and the contact angle distribution of particles in force chains was found to be well aligned in the directions of major principal stress.

关键词: granular matter     force chain     multiscale modeling    

Motion/force transmission indices of parallel manipulators

Xinjun LIU, Chao WU, Fugui XIE

《机械工程前沿(英文)》 2011年 第6卷 第1期   页码 89-91 doi: 10.1007/s11465-011-0215-1

Applications of atomic force microscopy in immunology

Jiping Li, Yuying Liu, Yidong Yuan, Bo Huang

《医学前沿(英文)》 2021年 第15卷 第1期   页码 43-52 doi: 10.1007/s11684-020-0769-6

摘要: Cellular mechanics, a major regulating factor of cellular architecture and biological functions, responds to intrinsic stresses and extrinsic forces exerted by other cells and the extracellular matrix in the microenvironment. Cellular mechanics also acts as a fundamental mediator in complicated immune responses, such as cell migration, immune cell activation, and pathogen clearance. The principle of atomic force microscopy (AFM) and its three running modes are introduced for the mechanical characterization of living cells. The peak force tapping mode provides the most delicate and desirable virtues to collect high-resolution images of morphology and force curves. For a concrete description of AFM capabilities, three AFM applications are discussed. These applications include the dynamic progress of a neutrophil-extracellular-trap release by neutrophils, the immunological functions of macrophages, and the membrane pore formation mediated by perforin, streptolysin O, gasdermin D, or membrane attack complex.

关键词: cellular mechanics     atomic force microscopy     neutrophil extracellular trap     macrophage phagocytosis     pore formation    

标题 作者 时间 类型 操作

protein on PVDF ultrafiltration membrane fouling behavior under different pH conditions: interface adhesionforce and XDLVO theory analysis

Xudong WANG,Miao ZHOU,Xiaorong MENG,Lei WANG,Danxi HUANG

期刊论文

On the applicability of different adhesion models in adhesive particulate flows

Guanqing LIU, Shuiqing LI, Qiang YAO,

期刊论文

大力测量技术的新进展——附着式超轻型大力传感器

沈久珩

期刊论文

Materials and surface engineering to control bacterial adhesion and biofilm formation: A review of recent

Huan GU, Dacheng REN

期刊论文

Effect of electrokinetic property of charged polyether sulfone membrane on bovine serum albumin fouling behavior

Xiaorong Meng, Shanshan Huo, Lei Wang, Xudong Wang, Yongtao Lv, Weiting Tang, Rui Miao, Danxi Huang

期刊论文

Effect of interface adhesion factor on the bearing capacity of strip footing placed on cohesive soil

期刊论文

Study on the cohesion and adhesion of hot-poured crack sealants

Meng GUO, Yiqiu TAN, Xuesong DU, Zhaofeng LV

期刊论文

CD176 single-chain variable antibody fragment inhibits the adhesion of cancer cells to endothelial cells

null

期刊论文

Modeling limit force capacities of high force to volume lead extrusion dampers

期刊论文

Plated contacts for solar cells with superior adhesion strength to screen printed solar cells

R. CHEN,S. WANG,A. WENHAM,Z. SHI,T. YOUNG,J. JI,M. EDWARDS,A. SUGIANTO,L. MAI,S. WENHAM,C. CHONG

期刊论文

Development and road performance of clear asphalt with high transparency and adhesion

期刊论文

Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

期刊论文

Visualization of force networks in 2D dense granular materials

Jianguo LIU, Qicheng SUN, Feng JIN,

期刊论文

Motion/force transmission indices of parallel manipulators

Xinjun LIU, Chao WU, Fugui XIE

期刊论文

Applications of atomic force microscopy in immunology

Jiping Li, Yuying Liu, Yidong Yuan, Bo Huang

期刊论文